![]() ![]() We can see this more clearly if, for example, we expand the spectrum in the region of the 3 d emission. The 3 d photoemission is in fact split between two peaks, one at 334.9 eV BE and the other at 340.2 eV BE, with an intensity ratio of 3:2. ![]() The inner core electronic configuration of the initial state of the Pd is : This arises from spin-orbit coupling effects in the final state.
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